Coupling Constants
Energy level of a nuclei are affected by covalently-bonded neighbors spin-states
three-bond
one-bond
Spin-States of covalently-bonded nuclei want to be aligned.
+J/4
J (Hz)
bb
I
S
a
b
b
a
-J/4
S
I
I
S
aa
+J/4
The magnitude of the separation is called
coupling constant
(
J
) and has units
of Hz.