Beer’s Law
• A
= e bC (Beer’s Law)
•where e = molar
absorptivity (units M-1cm-1 ); b = sample thickness (cell pathlength) in cm; and C = conc. in M (mol/L). , is a property of the analyte and of wavelength; identification of the analyte
•(qualitative analysis) is possible from the spectrum (e vs 8). Note that
the sensitivity m is equal to e
b.
•