Test 6 (20 points), C98
1. (5 points) Sulfur forms the hexafluoride, SF6, which is completely unreactive toward water. In contrast, the selenium and tellurium analogs react with water (this reaction is called hydrolysis). Propose products for the reaction of SeF6 with H2O. Explain why the S and Se hexafluorides show such different reactivity toward water (hint: a thermodynamic argument won't work here; both compounds are thermodynamically unstable to hydrolysis.)
2. (5 points) Several interesting structures are shown in Figure 9.5, page 330 of Wulfsberg. Draw Lewis structures for S2N2 (d) and (NPF2)3 (e).
3. (5 points) On page 320 of Wulfsberg, under Group 14/4A, you will find the statement that "SnF4 has a polymeric structure with bridging by half of the fluorine atoms." Propose a structure consistent with this statement.
4. (5 points) A chemist claims that he has synthesized a compound of formula NH5. He suggests two possible structures for the compound. The first suggestion is that the compound consists of NH5 molecules in which the stereochemistry at N is trigonal bipyramidal. The second suggestion is that the compound is ionic, with NH4+ cations and H- anions. Critique these two suggestions using as many structural principles as possible.