Chapter 12

·         Be able to write Lewis symbols of elements and predict the number covalent bonds and ionic charge

·         Be able to tell polarity (non-polar/polar/ionic) based on electronegativity of a covalent bond

·         Be able to draw Lewis structures of organic molecules

·         Be able to label the hybridization of carbon, oxygen and nitrogen in compounds

·         Be able to identify functional groups and types of organic compounds

·         12.1 Know the difference between organic and inorganic compounds

·         12.2 Describe the bonding characteristics of the carbon atom

·         12.3 Describe and select hydrocarbons and hydrocarbon derivatives

·         12.4 Know the types of alkanes: acyclic saturated hydrocarbons: normal and branced

·         12.5 Structural Formulas

·         12.6 Alkane Isomerism

·         12.7 Conformations of Alkanes

·         12.8 IUPAC Nomenclature for Alkanes

·         12.9 Line-Angle Formulas for Alkanes

·         12.10 Classification of Carbon Atoms

·         12.11 Branched-Chain Alkyl Groups

·         12.12 Cycloalkanes

·         12.13 IUPAC Nomenclature for Cycloalkanes

·         12.14 Isomerism in Cycloalkanes

·         12.15 Sources of Alkanes and Cycloalkanes

·         12.16 Physical Properties of Alkanes and Cycloalkanes

·         12.17 Chemical Properties of Alkanes and Cycloalkanes

·         Be able to determine molecular formula from,  condensed, structural, a line-angle formula Know IUPAC nomenclature for simple (unbranched) alkanes

·         Be able to draw constitutional isomers (Lewis structures or condensed formulas as specified) given the molecular formula

·         Know the names of common alkyl groups found on branched alkanes

·         Know IUPAC nomenclature for normal alkanes

·         Know IUPAC nomenclature for complex (branched) alkanes

·         Be able to identify primary, secondary and tertiary carbons on a organic compound

·         Know what a Newman projection (staggered/ecliped) is and what it represents along with the most and least stable conformers  

·         Know the naming of simple and  substituted cycloalknes

·         Know cyclepentane and cyclohexane conformations (most stable and least stable)

·         Know cis/trans geometric isomerism in cycloalakne compounds

·         Know structure and physical property trends  (you do not need to know the exact melting point or boiling point for a specific alkane).

·         Know combustion and substation reactions of alkanes and cycloalkanes.

 

Chapter 13

13. Unsaturated Hydrocarbons

13.1 Unsaturated Hydrocarbons

13.2 Characteristics of Alkenes and Cycloalkenes

13.3 Names for Alkenes and Cycloalkenes

13.4 Line-Angle Formulas for Alkenes

13.5 Isomerism in Alkenes

13.6 Naturally Occurring Alkenes

13.7 Physical Properties of Alkenes

13.8 Chemical Reactions of Alkenes

13.9 Polymerization of Alkenes: Addition Polymers

13.10 Alkynes

Chemistry at a Glance: Chemical Reactions of Alkenes

Chemistry at a Glance: IUPAC Nomenclature for Alkanes, Alkenes, and Alkynes

13.11 Aromatic Hydrocarbons

13.12 Names for Aromatic Hydrocarbons

13.13 Aromatic Hydrocarbons: Physical Properties and Sources

13.14 Chemical Reactions of Aromatic Hydrocarbons

 

·         Know IUPAC nomenclature for alkenes and alkynes

·         Be able to determine different types of isomerism: constitutional, conformational and stereo ismoers

·         Know cis/trans geometric isomerism (stereo ismoers ) in alkenes

·         Be able to determine the number of units of unsaturation in a compound

·         Be able to identify isoprene units in terpenes

·         Know combustion and addition  reactions of alkanes and cycloalkanes.

·         Know nomenclature for simple aromatic compounds

·          

 

Chapter 14

·         Be able to classify reactions as substitution, rearrangement, addition or elimination (like chapter 5 slides 5 and HW4 problem 3).

·         Be able to identify the steps on a potential diagram for a chemical reaction (pg. 121-122).

·         Be able to identify the  polarity [nucleophiles (Nu:-)/eletrophiles (E+)], identify Lewis acid (E+)/base (Nu:-) sites and thus determine the reactive sites in a molecule to predict mechanistic steps (like 4.8, 4.9 and 4.11 pgs.100 and 102).

·         Know the mechanism of electrophilic addition (see general mechanism pg.120).

·         Be able to determine the most stable carbocation (like 5.3 pg.128).

·         Know preparations of alkenes by dehydrohalogenation and alkenes by dehydration of alcohols.  This includes knowing the reagents necessary to carry out these reactions (Like key reactions given in page 137).

·         Know the products of electrophilic addition to an alkene depending on the reagents ((Like key reactions given in page 137 and stability of carbocation)

·         Be able to recognize the correctly written mechanism for hydration of an alkene to an alcohol (Like 5.6 pg.130).

·         Be able to recognize the correctly written mechanism for hydrohalogenation an alkene to an haloalkane(5.4 pg. 128).

·         Be able to identify regio- and stereo-selective electrophilic addition reactions (5.23 pg. 139).

·         Be able to apply Markovnikov's rule(Like 5.5 pg.129).