Notes
Slide Show
Outline
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Chapter 7
  • Gases, Liquids, and Solids
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Gases, Liquids, and Solids
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Hydro-power from potential energy
  • Fig. 7.1
  • The water in the lake behind the dam has potential energy as a result of its position.
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Kinetic Energy and Collisions
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Properties of Gases, Liquids, and Solids
  • Table 7.1
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Arrangement of Particles in three States
  • Fig. 7.3
  • (a) In a solid, the particles are close together. (b) In a liquid, the particles slide freely over one another. (c) In a gas, the particles are in random motion.
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Gases in random motion
  • Fig. 7.4
  • Gas molecules can be compared to billiard balls in random motion, bouncing off one another.
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Popping into different states
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Compressibility of gases
  • Fig. 7.5
  • When a gas is compressed, the amount of empty space in the container is decreased.
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Barometer: Measuring the Pressure of gases
  • Fig. 7.6
  • The essential components of a mercury barometer are a graduated glass tube, a glass dish, and liquid mercury.
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Boyle and the gas Laws
  • Fig. 7.7
  • Robert Boyle was self-taught. Through his efforts, the true value of experimental investigation was first recognized.
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Boyles’ Law:
  • Fig. 7.8
  • Data illustrating the inverse proportionality associated with Boyle’s law.
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Charles Law
  • Fig. 7.9      When the volume of a gas at constant temperature decreases by half, the average number of times a molecule hits the container walls is doubled.
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Application of Boyle’s Law
  • Fig. 7.10
  • Filling a syringe with a liquid is an application of Boyle’s law.
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Charles and gas laws
  • Fig. 7.11
  • Jacques Charles in the process of working with hot-air balloons made the observations that led to the formulation of what is now known as Charles’s law.
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Charles Law
  • Fig. 7.12
  • Data illustrating the direct proportionality associated with Charles’s law.
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Dalton and the Partial Pressure
  • Fig. 7.13
  • John Dalton had an interest in the study of weather.
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Dalton’s law of partial pressures
  • Fig. 7.14                                                                                               A set of four containers can be used to illustrate Dalton’s law of partial pressures. The pressure in the fourth container equals the sum of the first three.
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Blood gases and their solubilty
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Summary of gas laws
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Changes of states
  • Fig. 7.15
  • There are six changes of state possible for substances.
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Sublimation of Iodine
  • The beaker contains iodine crystals.
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Vapor pressure and equilibrium
  • Fig. 7.17
  • (a) the liquid level drops for a time, (b) then becomes constant. At that point a state of equilibrium has been reached in which (c) the rate of evaporation equals the rate of condensations.
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Boiling point of liquids
  • Fig. 7.18
  • Bubbles of vapor form within a liquid when the temperature of the liquid reaches the liquid’s boiling point.
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How you cook? Low or high pressure
  • Fig. 7.19
  • The converse of the pressure cooker “phenomenon” is that food cooks more slowly at reduced pressure.
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Intermolecular forces: Dipole-dipole
  • Fig. 7.20
  • There are many dipole-dipole interactions possible between randomly arranged CIF molecules.
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Vapor pressure and the temperature
  • Table 7.2


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Pressure cooker: how does it work?
  • Table 7.4


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Boiling point and Eelvation
  • Table 7.3


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Strongest intermolecular force:
The hydrogen bonding
  • Fig. 7.21
  • Depiction of hydrogen bonding among the water molecules.
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Three types of hydrogen bonding
  • Fig. 7.22
  • Diagrams of hydrogen bonding involving selected simple molecules.
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Hydrogen bonding in ice
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How does hydrogen bonding affect properties
  • Fig. 7.23
  • If there were no hydrogen bonding between water molecules, the boiling point of water would be approximately
    -80C.
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London Dispersion Forces:
  • Fig. 7.24
  • Nonpolar molecules can develop instantaneous dipoles and induced dipoles.
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Summary of intermolecular forces