1
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- Chemical Bonding: The Covalent Bond Model
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2
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3
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- Fig. 5.1
- Electron sharing can occur only when electron orbitals from two
different atoms overlap.
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4
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- Fig. 5.2
- The number of covalent bonds formed by a nonmetallic element is
directly correlated with the number of electrons it must share in order
to obtain an octet of electrons.
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5
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- Fig. 5.3 (a) A “regular”
covalent single bond is the result of overlap of two half-filled
orbitals. (b) A coordinate covalent single bond is the result of overlap
of a filled and a vacant orbital.
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6
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- Fig. 5.4
- The sulfur dioxide molecule.
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7
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- Fig. 5.5
- The phosphorus trifluoride molecule.
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8
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- Fig. 5.6
- The hydrogen cyanide molecule.
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9
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10
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- Fig. 5.7
- The sulfate ion.
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11
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- Fig. 5.8
- Arrangement of valence electron pairs about a central atom that
minimize repulsions between the pairs.
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12
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13
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- Fig. 5.9
- (a) Acetylene molecule. (b) Hydrogen peroxide molecule. (c) Hydrogen
azidde molecule.
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14
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15
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- Fig. 5.10
- Linus Pauling received the Nobel Prize in chemistry in 1954 for his
work on the nature of the chemical bond.
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16
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- Fig. 5.11
- Abbreviated periodic table showing Pauling electronegativity values for
selected representative elements.
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17
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- Fig. 5.12
- (a) In the nonpolar covalent bond present, there is a symmetrical
distribution of electron density. (b) In the polar covalent bond
present, electron density is displaced because of its electronegativity.
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18
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19
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- Fig. 5.13
- (a) Methane is a nonpolar tetrahedral molecule. (b) Methyl chloride is a polar
tetrahedral molecule.
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20
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21
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22
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- Fig. 5.14
- The tetraphosphorous decoxide molecule.
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