Notes
Slide Show
Outline
1
Chapter 5
  • Chemical Bonding: The Covalent Bond Model
2
What’s the fuel in space shuttle?
3
Hydrogen molecule: A covalent bond
  • Fig. 5.1
  • Electron sharing can occur only when electron orbitals from two different atoms overlap.
4
Number of covalent bonds and Lewis symbol
  • Fig. 5.2
  • The number of covalent bonds formed by a nonmetallic element is directly correlated with the number of electrons it must share in order to obtain an octet of electrons.
5
Covalent and Coordinate covalent  Bond
  • Fig. 5.3   (a) A “regular” covalent single bond is the result of overlap of two half-filled orbitals. (b) A coordinate covalent single bond is the result of overlap of a filled and a vacant orbital.
6
Molecular structure
  • Fig. 5.4
  • The sulfur dioxide molecule.
7
Pyramidal molecule
  • Fig. 5.5
  • The phosphorus trifluoride molecule.
8
Linear Molecule
  • Fig. 5.6
  • The hydrogen cyanide molecule.
9
Unpaired electrons
10
Polyatomic ions held by covalent bonds
  • Fig. 5.7
  • The sulfate ion.
11
Electron pair repulsions
  • Fig. 5.8
  • Arrangement of valence electron pairs about a central atom that minimize repulsions between the pairs.
12
Where you find covalent molecules?
13
Space filling models
  • Fig. 5.9
  • (a) Acetylene molecule. (b) Hydrogen peroxide molecule. (c) Hydrogen azidde molecule.
14
VSEPR theory and molecular geometry
15
Linus Pauling and Electronegativity
  • Fig. 5.10
  • Linus Pauling received the Nobel Prize in chemistry in 1954 for his work on the nature of the chemical bond.
16
Electronegativity Trends
  • Fig. 5.11
  • Abbreviated periodic table showing Pauling electronegativity values for selected representative elements.
17
Polarity in heteonuclear diatomic molecules
  • Fig. 5.12
  • (a) In the nonpolar covalent bond present, there is a symmetrical distribution of electron density. (b) In the polar covalent bond present, electron density is displaced because of its electronegativity.
18
Types of covalent bond
19
Predicting polarity of molecule
  • Fig. 5.13
  • (a) Methane is a nonpolar tetrahedral molecule.       (b) Methyl chloride is a polar tetrahedral molecule.
20
Prefixes for naming covalent compounds
  • Table 5.1
21
Common names of covalent compunds
  • Table 5.2
22
Naming covalent compounds
  • Fig. 5.14
  • The tetraphosphorous decoxide molecule.