Chemistry 122 - Lecture to accompany Experiment 3: Activity Series of Metals

BALANCING EQUATIONS
Balanced equations obey the law of conservation of mass.

The total mass before a reaction takes place will equal the total mass after the reaction is complete.

The number of atoms which take part in a chemical reaction will also remain constant.

Balancing an equation can sometimes involve trial and error. The following rules and suggestions can
go a long way in keeping down the errors.

1. The equation will be understood to proceed from left to right. The reactants are on the left side of
    the arrow and the products are on the right.

2 H2 + O2 ----> 2 H2O
     Reactants          Products

2. Equations are balanced by adjusting COEFFICIENTS in front of formulas, never by changing
    subscripts within formulas.  Remember that a 1 is understood when a coefficient is not present.

3. It is best to start with an element that appears in only one compound on each side of the arrow.

4. Next balance any element that appears in more than one compound on either the right or left.

5. Balance free elements last. That is balance any element that appears in elemental form on the
    right or left.

6. When polyatomic species (NH4+, SO4-2, OH-, etc.) appear on both sides of the arrow in
    compounds or as ions, balance them as units rather than individual elements.

7. Leave the coefficients in the lowest whole number ratio.



EXAMPLE 1
     Mg +     O2 ---->      MgO
 
 
 

EXAMPLE 2
     C2H8N2     N2O4 ---->     N2     H2O +      CO2
 
 
 

EXAMPLE 3
     Fe2(SO4)3     BaCl2 ---->     BaSO4     FeCl3
 
 
 

EXAMPLE 4
     H3PO4    Ca(OH)2 ---->      Ca3(PO4)2     H2O
 
 

COMBUSTION REACTIONS
Combustion is a chemical reaction in which a substance reacts with oxygen, usually with the
rapid release of heat to produce a flame.  We will limit our discussion to the complete combustion
of hydrocarbons.   Hydrocarbons react (combust) with oxygen to yield carbon dioxide and water.

EXAMPLE 5
     CH4(g) +      O2(g) --->       CO2(g) +       H2O(g)
 
 
 

EXAMPLE 6
     C2H6(g) +      O2(g) --->      CO2(g) +       H2O(g)
 
 
 

EXAMPLE 7
     C4H10(g) +     O2(g) --->      CO2(g) +       H2O(g)