MOLE (mol)
The mole is the SI unit for amount of a substance.
The mole is the quantity of a substance which contains
as many individual units (e.g. moleucles,
formula units, atoms) as there are atoms in exactly
0.012 kg (12 g) of carbon-12.
The number of units in a mole is 6.022 x1023 and is often referred to as Avogadro's number.
One mole of carbon-12 contains 6.022 x1023 atoms of carbon-12.
One mole of water contains 6.022 x1023 molecules of water.
The mole is defined so that a sample of an element
with a mass equal to its atomic mass in
grams contains Avogadro's number of that element.
There are 22.99 g of sodium in one mole of sodium
metal. There are 10.81 g of boron in one
mole of elemental boron.
The mass of one mole in grams of a substance is called the molar mass.
EXAMPLE 1
How many moles are there in a 11.5 gram sample of sodium metal?
[11.5 g Na][1 mol Na/23.00 g Na] = 0.500 mol Na
EXAMPLE 2
What is the mass of 0.125 mol of boron?
[0.125 mol B][10.81 g B/1 mol B] = 1.35 g B
MOLAR MASS OF COMPOUNDS
The molar mass of a compound is equal to the sum of the atomic
masses of the atoms
composing the compound.
EXAMPLE 3
What is the molar mass of H2O?
2 H @ 1.01 g =
2.02 g
1 O @ 16.00 g = 16.00 g
18.02 g/mol
EXAMPLE 4
What is the mass of 19.70 mol of water?
[19.70 mol H2O][18.02 g H2O/mol H2O] = 355.0 g H2O
EXAMPLE 5
How many moles are in a 1.00 gram sample of of potassium sulfate, K2SO4?
[1.00 g K2SO4][1 mol K2SO4/174.27
g K2SO4] = 5.74 x 10-3 mol K2SO4
Some examples of hydrates are:
CuSO4 .5 H2O Copper(II) sulfate pentahydrate
NiSO4 .6 H2O Nickel(II) sulfate hexahydrate
AlK(SO4)2 .12 H2O Aluminum potassium sulfate dodecahydrate
When determining the molar mass for a hydrate the waters of hydration must be included.
EXAMPLE 6
What is the molar mass of copper(II) sulfate pentahydrate, CuSO4.5
H2O?
1 Cu @ 63.55 g = 63.55 g
1 S @ 32.07 g = 32.07 g
9 O @ 16.00 g = 144.00 g
10 H @ 1.01 g = 10.10 g
249.72 g/mol